(326)Analytical Chemistry of Nitrogen Compounds IV

ORGANIC CHEMISTRY Organic Compounds containing Nitrogen

Inorganic sulfur-nitrogen compounds: from gunpowder chemistry to the forefront of biological signaling.

The reactions between inorganic sulfur and nitrogen-bearing compounds to form S-N containing species have a long history and, besides assuming importance in industrial synthetic processes, are of relevance to microbial metabolism; waste water treatment; aquatic, soil and atmospheric chemistry; and combustion processes. The recent discovery that hydrogen sulfide and nitric oxide exert often simi...

Organo-nitrogen Compounds from Molecular Nitrogen

INTRODUCTION Industrial nitrogen fixation plays an important role in sustaining approximately 40% of the Earth’s population through generation of synthetic fertilizers. Annually, ca. 500 million tons of anhydrous ammonia, ammonium nitrate, and urea are produced through the Haber-Bosch process, which requires harsh conditions (200 atm, 450-500C) and affords low yields 10-20%. It has been estimat...

Manure Management regarding Nitrogen Compounds

This chapter considers the emissions of ammonia (NH 3) and nitrous oxide (N 2 O) from the excreta of agricultural animals deposited in buildings and collected as either liquid slurry or solid manure. This includes emissions from animal excreta at all stages: animal housing, manure storage and from land spreading of manures. Excreta deposited in fields by grazing animals are dealt with under SNA...

Introduction of Medicinal Chemistry & Heterocyclic Compounds